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This paper studies autoignition characteristics and HCCI engine combustion of ketone fuels, which are important constituents of recently discovered fungi-derived biofuels. Two ketone compounds, 2,4-dimethyl-3-pentanone (DMPN) and cyclopentanone (CPN), are systematically investigated in the Sandia HCCI engine, and the results are compared with conventional gasoline and neat ethanol. It is found that CPN has the lowest autoignition reactivity of all the biofuels and gasoline blends tested in this HCCI engine. The combustion timing of CPN is also the most sensitive to intake-temperature (Tin) variations, and it is almost insensitive to intake-pressure (Pin) variations. These characteristics and the overall HCCI performance of CPN are similar to those of ethanol. In contrast, DMPN shows multi-faceted autoignition characteristics. On the one hand, DMPN has strong temperature-sensitivity, even at boosted Pin, which is similar to the low-reactivity ethanol and CPN.

The lean-burn stratified-charge DISI engine has a strong potential for increased thermal efficiency compared to the traditional throttled SI engine. This experimental study of a spray-guided stratified-charge combustion system compares the engine response to injection-timing retard for gasoline and E85. Focus is on engine-out NO and soot, and combustion stability. The results show that for either fuel, injection-timing retard lowers the engine-out NO emissions. This is partly attributed to a combination of lower peak-combustion temperatures and shorter residence time at high temperatures, largely caused by a more retarded combustion phasing. However, for the current conditions using a single-injection strategy, the potential of NO reduction with gasoline is limited by both elevated soot emissions and the occurrence of misfire cycles. In strong contrast, when E85 fuel is used, the combustion system responds very well to injection-timing retard.

High-load HCCI combustion has recently been demonstrated with conventional gasoline using intake pressure boosting. The key is to control the high combustion heat release rates (HRR) by using combustion timing retard and mixture stratification. However, at naturally aspirated and moderately boosted conditions, these techniques did not work well due to the low autoignition reactivity of conventional gasoline at these conditions. This work studies a low-octane distillate fuel with similar volatility to gasoline, termed Hydrobate, for its potential in HCCI engine combustion at naturally aspirated and low-range boosted conditions. The HCCI combustion with fully premixed and partially stratified charges was examined at intake pressures (Pin) from 100 to 180 kPa and constant intake temperature (60°C) and engine speed (1200 rpm).

This study systematically investigates the effects of various engine operating parameters on the thermal efficiency of a boosted HCCI engine, and the potential of E10 to extend the high-load limit beyond that obtained with conventional gasoline. Understanding how these parameters can be adjusted and the trade-offs involved is critical for optimizing engine operation and for determining the highest efficiencies for a given engine geometry. Data were acquired in a 0.98 liter, single-cylinder HCCI research engine with a compression-ratio of 14:1, and the engine facility was configured to allow precise control over the relevant operating parameters. The study focuses on boosted operation with intake pressures (Pin) ≥ 2 bar, but some data for Pin < 2 bar are also presented. Two fuels are considered: 1) an 87-octane gasoline, and 2) E10 (10% ethanol in this same gasoline) which has a lower autoignition reactivity for boosted operation.

The combustion behavior of conventional gasoline has been numerically investigated by means of detailed chemical-kinetic modeling simulations, with particular emphasis on analyzing the chemistry of the intermediate temperature heat release (ITHR). Previous experimental work on highly boosted (up to 325 kPa absolute) HCCI combustion of gasoline (SAE 2020-01-1086) showed a steady increase in the charge temperature up to the point of hot ignition, even for conditions where the ignition point was retarded well after top dead center (TDC). Thus, sufficient energy was being released by early pre-ignition reactions resulting in temperature rise during the early part of the expansion stroke This behavior is associated with a slow pre-ignition heat release (ITHR), which is critical to keep the engine from misfiring at the very late combustion phasings required to prevent knock at high-load boosted conditions.

Isopentanol is an advanced biofuel that can be produced by micro-organisms through genetically engineered metabolic pathways. Compared to the more frequently studied ethanol, isopentanol's molecular structure has a longer carbon chain and includes a methyl branch. Its volumetric energy density is over 30% higher than ethanol, and it is less hygroscopic. Some fundamental combustion properties of isopentanol in an HCCI engine have been characterized in a recent study by Yang and Dec (SAE 2010-01-2164). They found that for typical HCCI operating conditions, isopentanol lacks two-stage ignition properties, yet it has a higher HCCI reactivity than gasoline. The amount of intermediate temperature heat release (ITHR) is an important fuel property, and having sufficient ITHR is critical for HCCI operation without knock at high loads using intake-pressure boosting. Isopentanol shows considerable ITHR, and the amount of ITHR increases with boost, similar to gasoline.

Ethanol and ethanol/gasoline blends are being widely considered as alternative fuels for light-duty automotive applications. At the same time, HCCI combustion has the potential to provide high efficiency and ultra-low exhaust emissions. However, the application of HCCI is typically limited to low and moderate loads because of unacceptably high heat-release rates (HRR) at higher fueling rates. This work investigates the potential of lowering the HCCI HRR at high loads by using partial fuel stratification to increase the in-cylinder thermal stratification. This strategy is based on ethanol's high heat of vaporization combined with its true single-stage ignition characteristics. Using partial fuel stratification, the strong fuel-vaporization cooling produces thermal stratification due to variations in the amount of fuel vaporization in different parts of the combustion chamber.

Tracer-based PLIF temperature diagnostics have been used to study the distribution and evolution of naturally occurring thermal stratification (TS) in an HCCI engine under fired and motored operation. PLIF measurements, performed with two excitation wavelengths (277, 308 nm) and 3-pentanone as a tracer, allowed investigation of TS development under relevant fired conditions. Two-line PLIF measurements of temperature and composition were first performed to track the mixing of the fresh charge and hot residuals during intake and early compression strokes. Results showed that mixing occurs rapidly with no measureable mixture stratification remaining by early compression (220°CA aTDC), confirming that the residual mixing is not a leading cause of thermal stratification for low-residual (4-6%) engines with conventional valve timing.

Homogeneous charge compression ignition (HCCI) combustion with fully premixed charge is severely limited at high-load operation due to the rapid pressure-rise rates (PRR) which can lead to engine knock and potential engine damage. Recent studies have shown that two-stage ignition fuels possess a significant potential to reduce the combustion heat release rate, thus enabling higher load without knock. This study focuses on three factors, engine speed, intake temperature, and fuel composition, that can affect the pre-ignition processes of two-stage fuels and consequently affect their performance with partial fuel stratification. A model fuel consisting of 73 vol.% isooctane and 27 vol.% of n-heptane (PRF73), which was previously compared against neat isooctane to demonstrate the superior performance of two-stage fuels over single-stage fuels with partial fuel stratification, was first used to study the effects of engine speed and intake temperature.

This study investigates the potential of partial fuel stratification for reducing the knocking propensity of intake-boosted HCCI engines operating on conventional gasoline. Although intake boosting can substantially increase the high-load capability of HCCI, these engines would be more production-viable if the knock/stability load limit could be extended to allow higher loads at a given boost and/or to provide even higher thermal efficiencies. A technique termed partial fuel stratification (PFS) has recently been shown to greatly reduce the combustion-induced pressure-rise rate (PRR), and therefore the knocking propensity of naturally aspirated HCCI, when the engine is fueled with a φ-sensitive, two-stage-ignition fuel. The current work explores the potential of applying PFS to boosted HCCI operation using conventional gasoline, which does not typically show two-stage ignition. Experiments were conducted in a single-cylinder HCCI research engine (0.98 liters) at 1200 rpm.

Long chain alcohols possess major advantages over the currently used ethanol as bio-components for gasoline, including higher energy content, better engine compatibility, and less water solubility. The rapid developments in biofuel technology have made it possible to produce C 4 -C 5 alcohols cost effectively. These higher alcohols could significantly expand the biofuel content and potentially substitute ethanol in future gasoline mixtures. This study characterizes some fundamental properties of a C 5 alcohol, isopentanol, as a fuel for HCCI engines. Wide ranges of engine speed, intake temperature, intake pressure, and equivalence ratio are investigated. Results are presented in comparison with gasoline or ethanol data previously reported. For a given combustion phasing, isopentanol requires lower intake temperatures than gasoline or ethanol at all tested speeds, indicating a higher HCCI reactivity.

The potential of boosted HCCI for achieving high loads has been investigated for intake pressures (Piⁿ) from 100 kPa (naturally aspirated) to 325 kPa absolute. Experiments were conducted in a single-cylinder HCCI research engine (0.98 liters) equipped with a compression-ratio 14 piston at 1200 rpm. The intake charge was fully premixed well upstream of the intake, and the fuel was a research-grade (R+M)/2 = 87-octane gasoline with a composition typical of commercial gasolines. Beginning with Piⁿ = 100 kPa, the intake pressure was systematically increased in steps of 20 - 40 kPa, and for each Piⁿ, the fueling was incrementally increased up to the knock/stability limit, beyond which slight changes in combustion conditions can lead to strong knocking or misfire. A combination of reduced intake temperature and cooled EGR was used to compensate for the pressure-induced enhancement of autoignition and to provide sufficient combustion-phasing retard to control knock.

The characteristics of ethanol autoignition and the associated HCCI performance are examined in this work. The experiments were conducted over wide ranges of engine speed, load and intake boost pressure (Piⁿ) in a single-cylinder HCCI research engine (0.98 liters) with a CR = 14 piston. The data show that pure ethanol is a true single-stage ignition fuel. It does not exhibit low-temperature heat release (LTHR), not even for boosted operation. This makes ethanol uniquely different from conventional distillate fuels and offers several benefits: a) The intake temperature (Tiⁿ) does not have to be adjusted much with changes of engine speed, load and intake boost pressure. b) High Piⁿ can be tolerated without running out of control authority because of an excessively low Tiⁿ requirement. However, by maintaining true single-stage ignition characteristics, ethanol also shows a relatively low temperature-rise rate just prior to its hot ignition point.

High-load HCCI operation is typically limited by rapid pressure-rise rates (PRR) and engine knock caused by an overly rapid heat-release rate (HRR). Exhaust gas recirculation (EGR) is commonly used in HCCI engines, and it is often stated in the literature that charge dilution with EGR (or high levels of retained residuals) is beneficial for reducing the PRR to allow higher loads without knock. However, EGR/retained-residuals affect other operating parameters such as combustion phasing, which can in turn influence the PRR independently from any effect of the EGR gases themselves. Because of the multiple effects of EGR, its direct benefit for reducing the PRR is not well understood. In this work, the effects of EGR on the PRR were isolated by controlling the combustion phasing independently from the EGR addition by adjusting the intake temperature. The experiments were conducted using gasoline as the fuel at a 1200 rpm operating condition.

Now more than ever, the increasing strictness of environmental regulation and the stronger need of higher efficiency standards are pushing for the development of cleaner and energy-efficient powertrains. HCCI engines are suitable candidates to achieve these objectives. Understanding the autoignition process and how it is affected by operating conditions is central to the development of these engines. In addition to experiments, detailed kinetic modeling represents a very effective tool for gaining deeper insight into the fundamentals of HCCI autoignition and combustion. Indeed, modeling activities are today widely used in engine design, allowing a significant reduction in prototype development costs and providing a valuable support to the improvement of control strategies.

This work explores how the high-load limits of HCCI are affected by fuel autoignition reactivity, EGR quality/composition, and EGR unmixedness for naturally aspirated conditions. This is done for PRF80 and PRF60. The experiments were conducted in a single-cylinder HCCI research engine (0.98 liters) with a CR = 14 piston installed. By operating at successively higher engine loads, five load-limiting factors were identified for these fuels: 1) Residual-NOx-induced run-away advancement of the combustion phasing, 2) EGR-NOx-induced run-away, 3) EGR-NOx/wall-heating induced run-away 4) EGR-induced oxygen deprivation, and 5) excessive partial-burn occurrence due to EGR unmixedness. The actual load-limiting factor is dependent on the autoignition reactivity of the fuel, the EGR quality level (where high quality refers to the absence of trace species like NO, HC and CO, i.e. simulated EGR), the level of EGR unmixedness, and the selected pressure-rise rate (PRR).

A planar temperature imaging diagnostic has been developed and applied to an investigation of naturally occurring thermal stratification in an HCCI engine. Natural thermal stratification is critical for high-load HCCI operation because it slows the combustion heat release; however, little is known about its development or distribution. A tracer-based single-line PLIF imaging technique was selected for its good precision and simplicity. Temperature-map images were derived from the PLIF images, based on the temperature sensitivity of the fluorescence signal of the toluene tracer added to the fuel. A well premixed intake charge assured that variations in fuel/air mixture did not affect the signal. Measurements were made in a single-cylinder optically accessible HCCI research engine (displacement = 0.98 liters) at a typical 1200 rpm operating condition. Since natural thermal stratification develops prior to autoignition, all measurements were made for motored operation.

Detailed exhaust speciation measurements were made on an HCCI engine fueled with iso-octane over a range of fueling rates, and over a range of fuel-stratification levels. Fully premixed fueling was used for the fueling sweep. This sweep extended from a fuel/air equivalence ratio (ϕ) of 0.28, which is sufficiently high to achieve a combustion efficiency of 96%, down to a below-idle fueling rate of ϕ = 0.08, with a combustion efficiency of only 55%. The stratification sweep was conducted at an idle fueling rate, using an 8-hole GDI injector to vary stratification from well-mixed conditions for an early start of injection (SOI) (40°CA) to highly stratified conditions for an SOI well up the compression stroke (325°CA, 35°bTDC-compression). The engine speed was 1200 rpm. At each operating condition, exhaust samples were collected and analyzed by GC-FID for the C1 and C2 hydrocarbon (HC) species and by GC-MS for all other species except formaldehyde and acetaldehyde.

One way to increase the load range in an HCCI engine is to increase boost pressure. In this modeling study, we investigate the effect of increased boost pressure on the fuel chemistry in an HCCI engine. Computed results of HCCI combustion are compared to experimental results in a HCCI engine. We examine the influence of boost pressure using a number of different detailed chemical kinetic models - representing both pure compounds (methylcyclohexane, cyclohexane, iso-octane and n-heptane) and multi-component models (primary reference fuel model and gasoline surrogate fuel model). We examine how the model predictions are altered by increased fueling, as well as reaction rate variation, and the inclusion of residuals in our calculations. In this study, we probe the low temperature chemistry (LTC) region and examine the chemistry responsible for the low-temperature heat release (LTHR) for wide ranges of intake boost pressure.

This work explores the high-load limits of HCCI for naturally aspirated operation. This is done for three fuels with various autoignition reactivity: iso-octane, PRF80, and PRF60. The experiments were conducted in a single-cylinder HCCI research engine (0.98 liter displacement), mostly with a CR = 14 piston installed, but with some tests at CR = 18. Five load-limiting factors were identified: 1) NOx-induced combustion-phasing run-away, 2) wall-heating-induced run-away, 3) EGR-induced oxygen deprivation, 4) wandering unsteady combustion, and 5) excessive exhaust NOx. These experiments at 1200 rpm show that the actual load-limiting factor is dependent on the autoignition reactivity of the fuel, the selected CA50, and in some cases, the tolerable level of NOx emissions. For iso-octane, which has the highest resistance to autoignition of the fuels tested, the NOx emissions become unacceptable at IMEPg = 473 kPa.